碳中和背景下的海水制氢路线

柯善超; 陈锐; 陈刚华; 刘明昊; 马学亮; 张泰基

doi:10.16513/j.2096-2185.DE.2106605

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分布式能源 ›› 2021, Vol. 6 ›› Issue (6) : 17-23. DOI: 10.16513/j.2096-2185.DE.2106605

学术研究

碳中和背景下的海水制氢路线

作者信息 +

Hydrogen Production From Seawater in Context of Carbon Neutrality

Author information +

文章历史 +

摘要

海洋是生命之源，如何进行海水资源高效开发利用是人类未来可持续发展的希望。氢能作为低碳时代的最佳能源选择，其在当下能源转型中扮演着重要角色。电解水制氢是公认的绿氢制备方法，然而其能耗以及水资源消耗问题却十分突出。随着风电等可再生能源逐渐深远海化，其导致的电力远距离输送的损耗问题也日益紧张。为了解决上述问题，通过可再生电力与海水淡化制氢以及海水化学资源利用可降低绿氢的综合生产成本，结合目前的海水资源利用技术以及可再生能源发展状况，该技术路线的经济性远大于海水直接电解技术。文章总结分析了目前海水制氢常用的两种方式，分析讨论了实现绿色氢经济的可行性发展方法及应用技术，以期为海水制氢相关研究及产业发展提供合理性参考。

Abstract

Ocean is the source of life, how to efficiently develop and utilize seawater resources is the hope of sustainable development of human beings in the future. As the best energy choice in the low-carbon era, hydrogen plays an important role in the energy transformation from fossil to green energy. Electrolysis of water is a recognized method of green hydrogen production, but its energy and water consumption are very prominent. With the development of renewable energy, the loss of long-distance transmission of renewable electricity is also becoming more and more serious. To solve the above problems, the comprehensive production cost of green hydrogen can be reduced through renewable electricity coupled with seawater hydrogen production after desalination and seawater chemical resource utilization. Combined with the development of seawater resource utilization and renewable energy currently, the economic efficiency of this route is much higher than that of direct seawater electrolysis. This paper summarizes and analyzes two common ways of hydrogen production from seawater at present, discusses the feasible development methods and application technologies to achieve green hydrogen economy, which provides reasonable reference for the relevant research and industrial development of hydrogen production from seawater.

导出引用

柯善超, 陈锐, 陈刚华, 等. 碳中和背景下的海水制氢路线[J]. 分布式能源. 2021, 6(6): 17-23 https://doi.org/10.16513/j.2096-2185.DE.2106605

Shanchao KE, Rui CHEN, Ganghua CHEN, et al. Hydrogen Production From Seawater in Context of Carbon Neutrality[J]. Distributed Energy Resources. 2021, 6(6): 17-23 https://doi.org/10.16513/j.2096-2185.DE.2106605

中图分类号： TK91

参考文献

列表( 原文顺序 | 文献年度倒序 | 文中引用次数倒序 ) 可视化分析

[1]	YU Z Y, DUAN Y, FENG X Y, et al. Clean and affordable hydrogen fuel from alkaline water splitting: Past, recent progress, and future prospects[J]. Advanced Materials, 2021, 33: 2007100. 本文引用 [1]

[2]	KE S C, CHEN R, CHEN G H, et al. Mini review on electrocatalyst design for seawater splitting: recent progress and perspectives[J]. Energy & Fuels, 2021, 35(16): 12948-12956. 本文引用 [1]

[3]	FARRAS P, STRASSER P, COWAN A J. Water electrolysis: Direct from the sea or not to be？[J]. Joule, 2021, 5(8): 1921-1923. 本文引用 [1]

[4]	BESWICK R R, OLIVEIRA A M, YAN Y. Does the green hydrogen economy have a water problem？[J]. ACS Energy Letters, 2021, 6(9): 3167-3169. 本文引用 [1]

[5]	HAUSMANN J N, SCHLOGL R, MENEZES P W, et al. Is direct seawater splitting economically meaningful？[J]. Energy & Environmental Science, 2021, 14(7): 3679-3685. 本文引用 [2]

[6]	KHAN M A, Al-ATTAS T, Roy S, et al. Seawater electrolysis for hydrogen production: a solution looking for a problem？[J]. Energy & Environmental Science, 2021, 14(9): 4831-4839. 本文引用 [1]

[7]

万晶晶，张军，王友转，等. 海水制氢技术发展现状与展望[J]. 世界科技研究与发展，2021,

https://doi.org/https://doi.org/10.16507/j.issn.1006-6055.2021.09.001

WAN

Jingjing

, ZHANG

Jun

, WANG

Youzhuan

, et al. Development status and prospect of hydrogen generation from seawater[J]. World Sci-Tech R & D, 2021,

https://doi.org/https://doi.org/10.16507/j.issn.1006-6055.2021.09.001

本文引用 [1]

[8]

申雪然，冯彩虹，代政，等. 电解海水制氢的研究进展[J]. 化工新型材料，2021,

https://kns.cnki.net/kcms/detail/11.2357.TQ.20210409.1045.002.html

SHEN

Xueran

, FENG

Caihong

, DAI

Zheng

, et al. Progress on hydrogen generation by splitting seawater[J]. New Chemical Materials, 2021,

http://kns.cnki.net/kcms/detail/11.2357.TQ.20210409.1045.002.html

本文引用 [1]

[9]	KUANG Y, KENNEY M J, MENG Y, et al. Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels[J]. Proceedings of the National Academy of Sciences, 2019, 116(14): 6624-6629. 本文引用 [2]

[10]	LI P, WANG S, SAMO I A, et al. Common-ion effect triggered highly sustained seawater electrolysis with additional NaCl production[J]. Research, 2020, 1-9. 本文引用 [2]

[11]	HUNG W H, XUE B Y, LIN T M, et al. A highly active selenized nickel-iron electrode with layered double hydroxide for electrocatalytic water splitting in saline electrolyte[J]. Materials Today Energy, 2021, 19: 100575. 本文引用 [2]

[12]	YU L, ZHU Q, SONG S, et al. Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis[J]. Nature Communications, 2019, 10(1): 5106. 本文引用 [2]

[13]	JADHAV A R, KUMAR A, LEE J, et al. Stable complete seawater electrolysis by using interfacial chloride ion blocking layer on catalyst surface[J]. Journal of Materials Chemistry A, 2020, 8: 24501-24514. 本文引用 [2]

[14]	LI J, LIU Y, CHEN H, et al. Design of a multilayered oxygen-evolution electrode with high catalytic activity and corrosion resistance for saline water splitting[J]. Advanced Functional Materials, 2021, 31(27): 2101820. 本文引用 [1]

[15]	WU L, YU L, ZHU Q, et al. Boron-modified cobalt iron layered double hydroxides for high efficiency seawater oxidation[J]. Nano Energy, 2021, 83: 105838. 本文引用 [1]

[16]	YU L, WU L, MCELHENNY B, et al. Ultrafast room-temperature synthesis of porous S-doped Ni/Fe (oxy)hydroxide electrodes for oxygen evolution catalysis in seawater splitting[J]. Energy & Environmental Science, 2020, 13: 3439-3446. 本文引用 [1]

[17]	CUI B, HU Z, LIU C, et al. Heterogeneous lamellar-edged Fe-Ni(OH)2/Ni3S2 nanoarray for efficient and stable seawater oxidation[J]. Nano Research, 2020, 14(4): 1149-1155. 本文引用 [1]

[18]	YU L, WU L, MCELHENNY B, et al. Rational design of core-shell-structured CoPx@FeOOH for efficient seawater electrolysis[J]. Applied Catalysis B: Environmental, 2021, 294: 120256 本文引用 [1]

[19]	MA T, XU W, LI B, et al. The critical role of additive sulfate for stable alkaline seawater oxidation on nickel-based electrodes[J]. Angewandte Chemie International Edition, 2021, 133(42): 22922-22926. 本文引用 [1]

[20]	SUN F, QIN J, WANG Z, et al. Energy-saving hydrogen production by chlorine-free hybrid seawater splitting coupling hydrazine degradation[J]. Nature communications, 2021, 12(1): 1-11. 本文引用 [2]

[21]	WEI X, LI Y, CHEN L, et al. Formic acid electro-synthesis by concurrent cathodic CO2 reduction and anodic CH3OH oxidation[J]. Angewandte Chemie International Edition, 2021, 60(6): 3148-3155. 本文引用 [2]

[22]	RIZO R, PEREZ-RODRIGUEZ S, GARCIA G. Well-defined platinum surfaces for the ethanol oxidation reaction[J]. ChemElectroChem, 2019, 18(6): 4725-4738. 本文引用 [1]

[23]	BOGGS B K, KING R L, BOTTE G G. Urea electrolysis: direct hydrogen production from urine[J]. Chemical Communications, 2009, 32: 4859-4861. 本文引用 [1]

[24]	HUANG Y, CHONG X, LIU C, et al. Boosting hydrogen production by anodic oxidation of primary amines over a NiSe nanorod electrode[J]. Angewandte Chemie International Edition, 2018, 130(40): 13347-13350. 本文引用 [1]

[25]	HUANG H, YU C, HAN X, et al. Ni, Co hydroxide triggers electrocatalytic production of high-purity benzoic acid over 400 mA cm^－2[J]. Energy & Environmental Science, 2020, 13(12): 4990-4999. 本文引用 [1]

[26]	LOGANATHAN P, NAIDU G, VIGNESWARAN S. Mining valuable minerals from seawater: a critical review[J]. Environmental Science: Water Research & Technology, 2017, 3(1): 37-53. 本文引用 [1]

[27]	田江南，安源，蒋晶，等. 碳中和背景下的脱碳方案[J]. 分布式能源，2021, 6(3): 63-69. TIAN Jiangnan, AN Yuan, JIANG Jing, et al. Technical solutions for decarburization in context of carbon neutrality[J]. Distributed Energy, 2021, 6(3): 63-69. 本文引用 [1]

[28]	BARDI U. Extracting minerals from seawater: An energy analysis[J]. Sustainability, 2010, 2(4): 980-992. 本文引用 [1]

[29]	D'AMORE-DOMENECH R, LEO T J. Sustainable hydrogen production from offshore marine renewable farms: Techno-energetic insight on seawater electrolysis technologies[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(9): 8006-8022. 本文引用 [1]

[30]	秦锋，秦亚迪，单彤文. 碳中和背景下氢燃料燃气轮机技术现状及发展前景[J]. 广东电力，2021, 34(10): 10-17 QIN Feng, QIN Yadi, SHAN Tongwen. Technology status and development prospects of hydrogen fuel gas turbine under the background of carbon neutral[J]. Guangdong Electric Power, 2021, 34(10): 10-17. 本文引用 [1]

[31]	卢一菲，陈冲，梁立中. 基于电—氢混合储能的风氢耦合系统建模与控制[J]. 智慧电力，2020, 48(3): 7-14. LU Yifei, CHEN Chong, LIANG Lizhong. Modeling and control of wind-hydrogen coupling system based on electricity-hydrogen hybrid energy storage[J]. Smart Power, 2020, 48(3): 7-14. 本文引用 [1]

[32]	雷超，李韬. 碳中和背景下氢能利用关键技术及发展现状[J]. 发电技术，2021, 42, (2): 207-217. LEI Chao, LI Tao. Key technologies and development status of hydrogen energy utilization under the background of carbon neutrality[J]. Power Generation Technology, 2021, 42, (2): 207-217. 本文引用 [1]