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碱性水电解制氢系统稳态建模研究
Steady-State Modeling Study on Hydrogen Production by Alkaline Water Electrolysis
碱性电解槽作为一种高效制氢技术,在绿氢制备中具有重要的应用前景。针对碱性水电解制氢系统,基于电化学原理和热力学分析,建立一个精确且适用性强的半理论半经验碱性电解槽模型。该模型将电解槽的小室电压和气体纯度视为工作压力、温度和电流密度的函数,并考虑法拉第效率对产氢速率的影响。基于文献中50 m3/h碱性电解槽在不同操作条件下的实验数据,通过非线性回归方法拟合得到模型参数,并利用实验数据来验证模型的准确性,同时分析了模型在不同操作条件下的适用性。研究结果表明,所提出的模型能够有效预测电解槽的性能参数,为电解槽的优化设计和控制系统开发提供了理论依据。
As an efficient hydrogen production technology, alkaline electrolyzer holds significant application prospects in green hydrogen production. For alkaline water electrolysis hydrogen production systems, this paper proposes an accurate and applicable semi-theoretical and semi-empirical alkaline electrolyzer model based on electrochemical principles and thermodynamic analysis. This model treats the electrolyzer’s cell voltage and gas purity as functions of operating pressure, temperature, and current density, and incorporates the influence of Faraday efficiency on hydrogen production rate. Based on literature-reported experimental data of a 50 m3/h alkaline electrolyzer under different operating conditions, this paper determines the model parameters via fitting using a nonlinear regression method. This paper further employs these experimental data to verify the model’s accuracy and analyze its applicability under varying operating conditions. The simulation results show that the proposed model can effectively predict the electrolyzer’s performance parameters, thereby providing a theoretical basis for the optimal design and the control systems of electrolyzers.
碱性电解槽 / 稳态建模 / 电化学反应 / 热力学分析 / 绿氢制备
alkaline electrolyzer / steady-state modeling / electrochemical reactions / thermodynamic analysis / green hydrogen production
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This paper introduces the sources of hydrogen,the development status of various hydrogen production technologies by electrolysis,focuses on the bottlenecks and development trends of membrane materials,catalysts and membrane electrode assemblies of proton exchange membrane (PEM) electrolysis,and analyzes the new application directions of PEM electrolysis worldwide.
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Hydrogen energy has broad development prospects as a clean, carbon-free, flexible and efficient secondary energy and industrial raw material. Although the technologies of hydrogen production by water electrolysis, hydrogen storage and hydrogen supply have been relatively mature, the technology chain of hydrogen production-storage-supply is still in its infancy. It is of great importance to explore the technology chain in power system for the cooperative utilization of hydrogen energy and traditional electricity. This paper firstly introduced the basic principles, classifications, advantages and disadvantages of the technologies including hydrogen production by water electrolysis, hydrogen storage and hydrogen supply, and summarized the development of hydrogen production by water electrolysis, hydrogen storage and hydrogen supply technologies in the United States, Japan and the European Union. Then, the current status of above technologies in China was analyzed, and three possible application modes of hydrogen production by water electrolysis, hydrogen storage and hydrogen supply in power system in China were discussed. Finally, based on the current situation, the suggestions for promoting the development of hydrogen production by water electrolysis, hydrogen storage and hydrogen supply in power system in China were put forward, which provide a reference for optimizing the development of the whole technology chain of hydrogen energy production-storage-supply-use. |
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