无烟煤中低负荷燃烧结渣特性及成分演化的实验研究

葛文韬, 陈猛, 王晨宇, 穆林, 东明, 王储

分布式能源 ›› 2026, Vol. 11 ›› Issue (3) : 14-22.

PDF(3664 KB)
PDF(3664 KB)
分布式能源 ›› 2026, Vol. 11 ›› Issue (3) : 14-22. DOI: 10.16513/j.2096-2185.DE.26110061
面向新型电力系统的煤电清洁高效与灵活运行关键技术

无烟煤中低负荷燃烧结渣特性及成分演化的实验研究

作者信息 +

Experimental Study on Slagging Characteristics and Composition Evolution of Anthracite Coal at Low to Medium Loads

Author information +
文章历史 +

摘要

针对无烟煤在锅炉中燃烧时灰渣易熔融沉积、影响运行安全与经济性的问题,依托0.4 MW一维沉降炉中试平台,系统开展了多种负荷、配风比例及过量空气系数条件下的燃烧试验。结合灰熔融特性、扫描电子显微镜(scanning electron microscope,SEM)、X射线衍射仪(X-ray diffraction,XRD)、X荧光光谱仪(X-ray fluorescence spectroscopy,XRF)及激光粒度分析等手段,深入研究了灰渣形貌、成分与粒度特性随工况的演变规律。结果表明,无烟煤灰渣主要由C、O、Si、Al元素组成,主要晶相为石英、莫来石和赤铁矿,不同工况下晶相类型保持稳定。当负荷由0.2 MW升至0.3 MW时,灰渣变形温度由1 259 ℃升至1 312 ℃,结渣指数由1 268增至1 319,结渣风险显著增强。一/二次风比由2/8提高至4/6,灰渣未燃碳质量分数可由约37.5%提高至40%,中位粒径由约22 μm可增大至约28 μm,沉积倾向明显加剧;相比之下,过量空气系数由1.2提高至1.4,对灰熔融特性及结渣指数的影响较小。粒度分布以细颗粒为主、粗颗粒并存的双峰特征,细颗粒形成黏附基底层,粗颗粒通过惯性撞击强化沉积,共同促进结渣发展。研究表明,负荷是影响无烟煤结渣行为的主导因素,配风方式通过调控燃尽与颗粒特性间接影响结渣倾向。该研究为宽负荷工况下无烟煤锅炉的结渣预测与燃烧优化提供了中试数据支撑。

Abstract

This study investigates the ash deposition behavior of anthracite during combustion, which significantly affects boiler safety and efficiency due to slagging tendencies. A pilot-scale one-dimensional settling furnace system was employed to conduct combustion experiments under varied operating conditions, including different loads, primary/secondary air ratios, and excess air coefficients. Ash samples were analyzed by fusion tests, scanning electron microscope(SEM), X-ray diffraction(XRD), X-ray fluorescence spectroscop(XRF), and laser sizing. Results show ash composition (C, O, Si, Al) and crystalline phases (quartz, mullite, hematite) remain stable. Increasing the load from 0.2 MW to 0.3 MW raises the ash deformation temperature from 1259 ℃ to 1312 ℃, while the slagging index increases from 1 268 to 1 319, indicating a significantly enhanced slagging tendency. When the mass ratio of primary air to secondary air is increased from 2/8 to 4/6, the unburned carbon content in ash increases from approximately 37.5% to 40%, and the median particle size enlarges from 22 μm to about 28 μm, resulting in a pronounced promotion of ash deposition. Excess air coefficient had limited impact on fusibility and slagging. Ash exhibited a bimodal size distribution: fine particles form an adhesive layer, while coarse particles deposit by impaction, jointly accelerating slagging. The results demonstrate that boiler load dominates slagging behavior, with air distribution affecting burnout and particle characteristics. This study provides pilot-scale experimental data and mechanistic insights for slagging prediction and combustion optimization of anthracite-fired boilers under wide-load operation.

关键词

无烟煤燃烧 / 一维沉降炉中试实验 / 灰渣特性 / 矿物转化 / 结渣倾向

Key words

anthracite coal combustion / one-dimensional settling furnace pilot-scale experiment / ash characteristics / mineral transformation / slagging tendency

引用本文

导出引用
葛文韬, 陈猛, 王晨宇, . 无烟煤中低负荷燃烧结渣特性及成分演化的实验研究[J]. 分布式能源, 2026, 11(3): 14-22 https://doi.org/10.16513/j.2096-2185.DE.26110061.
GE Wentao, CHEN Meng, WANG Chenyu, et al. Experimental Study on Slagging Characteristics and Composition Evolution of Anthracite Coal at Low to Medium Loads[J]. Distributed Energy, 2026, 11(3): 14-22 https://doi.org/10.16513/j.2096-2185.DE.26110061.
中图分类号: TK 22;TM 62   

参考文献

[1]
黄震, 谢晓敏, 张庭婷 “双碳”背景下我国中长期能源需求预测与转型路径研究[J]. 中国工程科学, 2022, 24(6): 8-18.
HUANG Zhen, XIE Xiaomin, ZHANG Tingting Medium-and long-term energy demand of China and energy transition pathway toward carbon neutrality[J]. Strategic Study of CAE, 2022, 24(6): 8-18.
[2]
尹昌洁, 权楠, 苏凯, 等 我国分布式能源发展现状及展望[J]. 分布式能源, 2022, 7(2): 1-7.
YIN Changjie, QUAN Nan, SU Kai, et al Status and outlook of distributed energy development in China[J]. Distributed Energy, 2022, 7(2): 1-7.
[3]
郭婷婷, 曹蕃 低碳能源系统发展趋势与应用实践[J]. 分布式能源, 2025, 10(1): 1-13.
GUO Tingting, CAO Fan Development trend and application of low-carbon energy system[J]. Distributed Energy, 2025, 10(1): 1-13.
[4]
苟伟, 张勋奎 “双碳”目标下支撑新一代煤电发展的关键技术[J]. 分布式能源, 2025, 10(5): 1-9.
GOU Wei, ZHANG Xunkui Key technologies supporting the development of next-generation coal-fired power under the goal of “carbon neutrality and carbon peaking”[J]. Distributed Energy, 2025, 10(5): 1-9.
[5]
TANG H, YAO G J, WANG Z B, et al Study on low-load combustion characteristics of a 600 MW power plant boiler with self-sustaining internal combustion burners[J]. Applied Thermal Engineering, 2025, 267: 125859.
[6]
李争起, 张鑫, 陈智超, 等 W火焰锅炉多次引射分级燃烧机理及技术研究[J]. 中国科学: 技术科学, 2020, 50(7): 849-862.
LI Zhengqi, ZHANG Xin, CHEN Zhichao, et al Multi-injection multi-staging combustion mechanistic studies and down-fired boiler technology[J]. Scientia Sinica (Technologica), 2020, 50(7): 849-862.
[7]
ZHANG X, CHEN Z C, ZHANG M D, et al Combustion stability, burnout and NO x emissions of the 300-MW down-fired boiler with bituminous coal: Load variation and low-load comparison with anthracite[J]. Fuel, 2021, 295: 120641.
[8]
张瀚霖, 周旭, 舒逸翔, 等 基于煤粉预气化强稳燃的快速调峰燃烧器5 MW中试研究[J]. 洁净煤技术, 2024, 30(9): 60-67.
ZHANG Hanlin, ZHOU Xu, SHU Yixiang, et al 5 MW pilot test study of rapid peaking burner based on pre-gasification strong stable combustion of pulverized coal[J]. Clean Coal Technology, 2024, 30(9): 60-67.
[9]
RODRIGUES S, MARQUES M, WARD C R, et al Mineral transformations during high temperature treatment of anthracite[J]. International Journal of Coal Geology, 2012, 94: 191-200.
[10]
BIAN L, LI Z, LU Y et al. Numerical simulation on combustion and slagging characteristics of a down-fired boiler under different blending ratios of anthracite/bituminous coal[J/OL]. Combustion Science and Technology, 2025: 1-29(2025-08-08)[2026-01-29]. https://doi.org/10.1080/00102202.2025.2541851.
[11]
HARIANA, PRISMANTOKO A, PRABOWO, et al Effectiveness of different additives on slagging and fouling tendencies of blended coal[J]. Journal of the Energy Institute, 2023, 107: 101192.
[12]
KUANG M, LI Z Q Review of gas/particle flow, coal combustion, and NOx emission characteristics within down-fired boilers[J]. Energy, 2014, 69: 144-178.
[13]
何宏舟. CFB锅炉洁净燃烧福建无烟煤的理论与试验研究[D]. 杭州: 浙江大学, 2005.
HE Hongzhou. Experimental and theoretical study on the cleaning combustion of Fujian anthracite in CFB boiler[D]. Hangzhou: Zhejiang University, 2005.
[14]
袁尧 探究通过燃烧调整降低NOx及飞灰含碳量的方法[J]. 能源与环境, 2022(1): 86-87.
YUAN Yao A study on methods to reduce NOx and carbon content in fly ash through combustion adjustment[J]. Energy and Environment, 2022(1): 86-87.
[15]
徐刚, 戴斌, 熊天洪, 等 耦合燃烧监测的W型火焰锅炉结渣特性实验研究[J]. 节能, 2025, 44(8): 122-127.
XU Gang, DAI Bin, XIONG Tianhong, et al Experimental study on slagging characteristics of W-shaped flame boilers coupled with combustion monitoring[J]. Energy Conservation, 2025, 44(8): 122-127.
[16]
孔维鑫, 吕毅, 代亮亮 600MW超临界“W”火焰锅炉劣质煤稳燃技术探究[J]. 云南水力发电, 2023, 39(6): 117-123.
KONG Weixin, LYU Yi, DAI Liangliang Exploration of stable combustion technology for inferior coal in 600 MW supercritical W flame boiler[J]. Yunnan Water Power, 2023, 39(6): 117-123.
[17]
章琪, 仇中柱, 杨文虎, 等 1000 MW燃煤锅炉宽负荷区炉内结焦和飞灰含碳量分析[J]. 环境工程, 2018, 36(9): 87-92.
ZHANG Qi, QIU Zhongzhu, YANG Wenhu, et al Investigation of slagging and carbon content of fly ash in a 1000 MW coal-fired boiler at wide load[J]. Environmental Engineering, 2018, 36(9): 87-92.
[18]
袁文杰, 贾小平, 李楠, 等 165 t/h CFB锅炉低负荷燃烧优化研究[J]. 洁净煤技术, 2020, 26(增刊1): 172-175.
YUAN Wenjie, JIA Xiaoping, LI Nan, et al Study on low load combustion optimizing of 165 t/h circulating fluidized bed boiler[J]. Clean Coal Technology, 2020, 26(S1): 172-175.
[19]
王高科, 郭伟勇, 黄鹏程, 等 宁夏宁东能源化工基地电厂粉煤灰的理化性质及资源化利用评价[J]. 再生资源与循环经济, 2023, 16(8): 20-25.
WANG Gaoke, GUO Weiyong, HUANG Pengcheng, et al Evaluation on physicochemical properties and resource utilization of fly ash from power plant in Ningxia Ningdong Energy Chemical Industry Base[J]. Recyclable Resources and Circular Economy, 2023, 16(8): 20-25.
[20]
王铁健, 闫文刚, 程海鹰, 等 煤粉燃烧火焰特征影响因素的分析研究[J]. 工程热物理学报, 2024, 45(12): 3906-3914.
WANG Tiejian, YAN Wengang, CHENG Haiying, et al Analysis and study on the influencing factors of flame characteristics in pulverized coal combustion[J]. Journal of Engineering Thermophysics, 2024, 45(12): 3906-3914.
[21]
高昕玥, 刘成昌, 翁君杰, 等 燃烧组织方式对烟煤-兰炭二元层燃过程中NO x生成特性的影响[J]. 煤炭转化, 2022, 45(3): 1-10.
GAO Xinyue, LIU Chengchang, WENG Junjie, et al Effects of combustion organization on NO x generation behaviors during the grate co-firing of bituminous coal with semi-coke[J]. Coal Conversion, 2022, 45(3): 1-10.
[22]
WANG C A, ZHOU L, FAN G F, et al Experimental study on ash morphology, fusibility, and mineral transformation during co-combustion of antibiotic filter residue and biomass[J]. Energy, 2021, 217: 119345.
[23]
NI Y G, HU S H, ZHANG Y Z, et al Research on the effects of the fly ash reburning on element migration and ash deposition characteristics of high-alkali coal in a full-scale slag-tapping boiler[J]. Fuel, 2023, 335: 126952.
[24]
资静斌, 王学斌, 邵鹏林, 等 纯烧高钠高氯煤的循环流化床锅炉设计与运行分析[J]. 热能动力工程, 2021, 36(4): 98-104.
ZI Jingbin, WANG Xuebin, SHAO Penglin, et al Design and operation analysis of CFB boiler burning high sodium and chlorine coal[J]. Journal of Engineering for Thermal Energy and Power, 2021, 36(4): 98-104.
[25]
TI S G, DENG S S, YANG Z, et al Industrial experimental study on combustion characteristics and NOx emission characteristics of a 600 MWe wall-fired boiler under ultra-low excess air coefficient conditions[J]. Asia-Pacific Journal of Chemical Engineering, 2025, 20(2): e3171.
[26]
RIBEIRO J, DABOIT K, FLORES D, et al Extensive FE-SEM/EDS, HR-TEM/EDS and ToF-SIMS studies of micron- to nano-particles in anthracite fly ash[J]. Science of the Total Environment, 2013, 452-453: 98-107.
[27]
李志坤, 姚锡文, 许开立, 等 生物质与烟煤混燃过程灰分的烧结特性研究[J]. 绿色矿冶, 2024, 40(3): 76-82.
LI Zhikun, YAO Xiwen, XU Kaili, et al Study on sintering characteristics of ash from combustion process of mixed biomass and bituminous coal[J]. Sustainable Mining and Metallurgy, 2024, 40(3): 76-82.
[28]
叶旭放, 陈志刚, 许崇涛, 等 工业锅炉能效分析与节能降碳路径探讨[J]. 节能技术, 2025, 43(5): 449-453.
YE Xufang, CHEN Zhigang, XU Chongtao, et al Analysis of energy efficiency in industrial boilers and exploration of energy conservation and carbon reduction pathways[J]. Energy Conservation Technology, 2025, 43(5): 449-453.
[29]
王志, 刘晋, 周俊杰, 等 高硫煤硫分、灰分随煤粒度变化的分布规律及分形特征[J]. 材料科学与工程学报, 2023, 41(2): 308-314.
WANG Zhi, LIU Jin, ZHOU Junjie, et al Distribution law and fractal characteristics of sulfur content and ash content in high sulfur coal with coal particle size change[J]. Journal of Materials Science and Engineering, 2023, 41(2): 308-314.

基金

国家重点研发计划项目(2024YFB4104801)
国家自然科学基金项目(52306283)
中央高校基本科研业务费资助项目(DUT24RC(33)073)

版权

版权所有©2026《分布式能源》编辑部
PDF(3664 KB)

Accesses

Citation

Detail

段落导航
相关文章

/